TITLE
Adirondack Lakes Survey Corporation Long-Term Monitoring Program: Stream Sampling.

PRINCIPAL COOPERATORS & CONTACTS
Karen Roy, New York State Department of Environmental Conservation
Mark Watson, New York State Energy Research and Development Authority
Steve Paulsen, U.S. Environmental Protection Agency.

OTHER COOPERATORS
Gregory B. Lawrence, U.S. Geological Survey, Troy, New York.
Howard A. Simonin, New York State Department of Environmental Conservation, Rome, New York
Charles T. Driscoll, Syracuse University
See references for additional cooperators.

BEGIN DATE
June 1992

END DATE
On-going

HISTORY AND LOCATION
The USEPA Episodic Response Project (ERP) was conducted from 1988 to 1990 to evaluate the occurrence and biological consequences of episodic acidification in northeastern U.S. streams. When the ERP concluded, the ALSC continued sampling of three ERP streams on a weekly interval as part if its long term monitoring program to determine responses from changes in atmospheric deposition. The study streams, Buck Creek, Bald Mountain Brook, and Fly Pond Outlet, are all located in the southwestern quadrant of the Adirondack Park.

SAMPLING DESIGN
Surface grab samples are collected from streams in deionized water-rinsed polyethylene bottles.

Each week samples are analyzed for lab pH, air-equilibrated pH, acid neutralizing capacity and specific conductivity. In addition, once each month samples are analyzed for the following additional parameters: trucolor, inorganic aluminum, organic aluminum, total dissolved aluminum, total monomeric aluminum, calcium, chloride, dissolved inorganic carbon, dissolved organic carbon, flouride, potassium, magnesium, sodium, ammonia, nitrite, silica and sulfate.

Concentration values are reported in mg/L ( instrument units ) for all parameters, with the following exceptions:
Specific conductance µ siemens/centimeter (µ S/cm)
pH pH units.
Color platinum-cobalt units PtCo
Aluminum µ g/L


Total dissolved, total monomeric and organic monomeric aluminum are analytically derived. Inorganic monomeric aluminum is calculated by subtracting organic monomeric from total monomeric aluminum.

REFERENCES
Baker,J.P., Van Sickle,J., Gagen,C.J., DeWalle,D.R., Sharpe,W.E., Carline,R.F., Baldigo,B.P., Murdoch,P.S., Bath,D.W., Kretser,W.A., Simonin,H.A., and Wigington,P.J., Jr. 1996. Episodic Acidification of Small Streams in the Northeastern United States: effects on fish populations. Ecological Applications 6: 422-437.

Van Sickle,J., Baker,J.P., Simonin,H.A., Baldigo,B.P., Kretser,W.A., and Sharpe,W.E. 1996. Episodic acidification of small streams in the northeastern United States: fish mortality in field bioassays. Ecological Applications 6: 408-421.

Wigington,P.J., Jr., Baker,J.P., DeWalle,D.R., Kretser,W.A., Murdoch,P.S., Simonin,H.A., Van Sickle,J., McDowell,M.K., Peck,D.V., and Barchet,W.R. 1996. Episodic acidification of small streams in the northeastern United States: Episodic Response Project. Ecological Applications 6: 374-388.

Wigington,P.J., Jr., DeWalle,D.R., Murdoch,P.S., Kretser,W.A., Simonin,H.A., Van Sickle,J., and Baker,J.P. 1996. Episodic acidification of small streams in the northeastern United States: ionic controls of episodes. Ecological Applications 6: 389-407.

Lawrence,G.B., Momen,B., and Roy,K.M. 2004. Use of stream chemistry for monitoring acidic deposition effects in the Adirondack region of New York. Journal of Environmental Quality 33: 1002-1009.

DATA ACCESS
Public access via the website www.adirondacklakessurvey.org Data represents samples taken from June 1992 to December 2004. Updates to the data set are planned in 2-3 year increments, following publication of current trend analyses.

DATA LOCATION
Adirondack Lakes Survey Corporation, Ray Brook, NY.

REVISION DATE
30 July 2005

CONTACT PERSON
Program Administrator
Adirondack Lakes Survey Corporation
1115 State Rte. 86
Ray Book, NY 12977
Telephone: 518.897.1360
www.adirondacklakessurvey.org

DATA ARCHIVE
The data archive is comprised of three files:

ALSC.Streams.2004.XLS Microsoft Excel™ spreadsheet that contains stream analytical data by sample and parameter. Detection limits are included on the second sheet of this spreadsheet.

ALSC.Streams.2004.CSV CSV Comma delimited ASCII file containing stream analytical data organized by sample and parameter.

STREAM_OVERVIEW This document.

EXPLANATORY NOTES
1. Missing data values are referenced by nulls ( blank space ). Note: Analysis of the full complement of chemical parameters is conducted only once each month. Parameters not analyzed on the interim sample dates are indicated by null values.

2 Data that do not meet the minimum charge balance criteria as defined by the EPA’s LTM Data Users Guide are flagged in the flag column.

3 Lab pH is stirred and unsparged with a seven-day holding time. Air-equilibrated pH is stirred and sparged for five minutes with a carbon dioxide / nitrogen mix and carries a seven-day holding time.


DETECTION LIMITS
Detection limits are presented on the second sheet of the MicroSoft Excel file contained in the archive.


DATA UPDATE FREQUENCY
The data set is updated every two to three years following ALSC’s QA/QC procedure and publication of updated trend analysis.



Publications using data from the Adirondack Long-Term Monitoring Program must include the following paragraph:
Some data used in this publication were obtained by cooperators of the Adirondack Lakes Survey Corporation's (ALSC) Long-Term Monitoring ( LTM ) Program. This publication has not been reviewed by the ALSC, nor has it been reviewed by the researchers or personnel of ALSC's cooperators. The LTM Program is operated by the ALSC which is supported by the New York State Energy Research and Development Authority and the New York State Department of Environmental Conservation, Division of Air Resources, with additional funding from the US Environmental Protection Agency.

Data Access Guidelines for Lake Chemistry
The public dissemination of these Adirondack Long-Term Monitoring data is very important to the Adirondack Lakes Survey Corporation - it is a responsibility we take very seriously. As stewards of these long-term data, our highest priorities are:

  1. to maintain the integrity of these data;
  2. to allow adequate time for quality assurance, analysis and publication of results by the principal investigator(s), and
  3. to properly acknowledge the appropriate funding sources, without whose support the data record would not exist.

Therefore, we ask that you adhere to the following guidelines as a matter of common courtesy and ethical responsibility, please:

  1. inform us of your plans to use these data.
  2. acknowledge the sources of funding used to collect these data in any report or manuscript that you submit. The Adirondack Long-Term Monitoring Program is funded by: the New York State Energy Research and Development Authority, the New York State Department of Environmental Conservation and the US Environmental Protection Agency.


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